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Lithiation of 2-(Chloroaryl)-2-methyl-1,3-dioxolanes and Application in Synthesis of New ortho-Functionalized Acetophenone Derivatives.

✍ Scribed by Gyula Lukacs; Marta Porcs-Makkay; Gyula Simig


Publisher
John Wiley and Sons
Year
2003
Weight
101 KB
Volume
34
Category
Article
ISSN
0931-7597

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The uC NMR spectra of 24 1,3-dioxoIane derivatives are reported in an attempt to propose parameters for the C-2, C-4 and C-5 shifts from the %Me and 4-Me substituents, based on the ring stereochemistry. These parameters are obtained from simultaneous equations, and clearly agree with those Calculate