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Lithiated rare-earth thiospinels and selenospinels

✍ Scribed by Pablo de La Mora; John B. Goodenough


Book ID
103245147
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
590 KB
Volume
70
Category
Article
ISSN
0022-4596

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We present a combined 57 Fe Mo¨ssbauer/X-ray diffraction (Rietveld analysis) study carried out on an In 16 Fe 8 S 32 spinel before and after chemical lithium insertion. To accommodate the new inserted cations in the structure, two mechanisms are observed. First, for a low lithium content, a cation m