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Liquid/liquid extraction separation of hafnium with amberlite La-1 from zirconium and other elements in citric acid solutions

✍ Scribed by C.P. Vibhute; S.M. Khopkar


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
373 KB
Volume
193
Category
Article
ISSN
0003-2670

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✦ Synopsis


Hafnium (10-110 lg ml-l) is quantitatively extracted at pH 4.6 from 0.01 M citric acid with 0.1 M Amberlite LA-1 in xylene; it can be stripped with 0.1 M perchloric acid and determined spectrophotometrically with xylenol orange at 540 nm. Hafnium can be separated from binary and multicomponent mixtures by selective extraction and backextraction. The method is suitable for determining hafnium in zircon.