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Liquid—liquid extraction of metal ions by the 6-membered N-containing macrocycle hexacyclen

✍ Scribed by S. Arpadjan; M. Mitewa; P.R. Bontchev


Book ID
118994941
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
314 KB
Volume
34
Category
Article
ISSN
0039-9140

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Two types of macrocychc Schti bases contammg either thlophene or phenol subumts were synthesized and the effect of hgand atoms on the hqmd-hqmd extractlon of blvalent transltlon metal Eons was studled The phenol groups m the macrocycle led to a large mcrease m the extractlon of transltlon metal ions

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The sulfide podand (an open-chain neutral multidentate ligand with six sulfur donor atoms) 1,12-di-2-tbienyl-2,5,8,lltetrathiadodecane (TTD) was synthesized. Its extracting properties were examined with 1,2-dichloroethane and 4-methylpentan-2-one as solvents. The reagent showed high selectivity for