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Liquid–liquid extraction of cadmium(II) by Cyanex 923 and its application to a solid-supported liquid membrane system

✍ Scribed by Ana María Rodríguez; Dulce Gómez-Límón; Francisco José Alguacil


Publisher
Wiley (John Wiley & Sons)
Year
2005
Tongue
English
Weight
112 KB
Volume
80
Category
Article
ISSN
0268-2575

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✦ Synopsis


Abstract

The extraction of cadmium(II) by Cyanex 923 (a mixture of alkylphosphine oxides) in Solvesso 100 from hydrochloric acid solution has been investigated. The extraction reaction is exothermic. The numerical analysis of metal distribution data suggests the formation of CdCl~2~.2L, HCdCl~3~.2L and H~2~CdCl~4~.2L (L = ligand) in the organic phase. The results obtained for cadmium(II) distribution have been implemented in a solid‐supported liquid membrane system. The influences of feed phase stirring speed (400–1400 min^−1^), membrane composition (carrier concentration: 0.06–1 mol dm^−3^) and metal concentration (0.01–0.08 g dm^−3^) on cadmium transport have been investigated. Copyright © 2005 Society of Chemical Industry


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