## Abstract The extraction of zinc(II) by Cyanex 923 (phosphine oxides mixture) in Solvesso 100 from hydrochloric acid solution has been investigated. The extraction reaction is exothermic. The numerical analysis of metal distribution data suggests the formation of ZnCl~2~·L~2~,HZnCl~3~·2L and H~2~
Liquid–liquid extraction of cadmium(II) by Cyanex 923 and its application to a solid-supported liquid membrane system
✍ Scribed by Ana María Rodríguez; Dulce Gómez-Límón; Francisco José Alguacil
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2005
- Tongue
- English
- Weight
- 112 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0268-2575
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The extraction of cadmium(II) by Cyanex 923 (a mixture of alkylphosphine oxides) in Solvesso 100 from hydrochloric acid solution has been investigated. The extraction reaction is exothermic. The numerical analysis of metal distribution data suggests the formation of CdCl~2~.2L, HCdCl~3~.2L and H~2~CdCl~4~.2L (L = ligand) in the organic phase. The results obtained for cadmium(II) distribution have been implemented in a solid‐supported liquid membrane system. The influences of feed phase stirring speed (400–1400 min^−1^), membrane composition (carrier concentration: 0.06–1 mol dm^−3^) and metal concentration (0.01–0.08 g dm^−3^) on cadmium transport have been investigated. Copyright © 2005 Society of Chemical Industry
📜 SIMILAR VOLUMES
## Abstract A method based on solid‐phase extraction coupled to liquid chromatography with positive ion electrospray ionization and tandem mass spectrometric detection was developed for the determination of didanosine in human serum, using lamivudine as internal standard. The acquisition was perfor