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Liquid Sulfur Dioxide as Solvent Medium for Chemical Reactions

โœ Scribed by Ross, John; Percy, J. H.; Brandt, R. L.; Gebhart, A. I.; Mitchell, J. E.; Yolles, Seymour

Book ID
124167838
Publisher
American Chemical Society
Year
1942
Weight
443 KB
Volume
34
Category
Article
ISSN
0019-7866

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Liquid Sulfur Dioxide as a Lewis-Acidic
Liquid Sulfur Dioxide as a Lewis-Acidic Solvent for the Alkylation and Alkoxyalkylation of Allylsilanes
โœ Prof. Dr. Herbert Mayr; Dipl.-Chem. Gorden Gorath; Bernhard Bauer ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 249 KB

from 1,2 H, additions to adjoining 6-5 bonds. The formation of this isomer is, however, unlikely because isolated X, addition to 6-5 bonds of C,, has never been observed and is calculated to be at least 20 kcalmol-' less stable than addition to 6-6 bonds at all levels of theory. The coupling consta