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Liquid-phase oxidation of isobutane—a reanalysis of the data

✍ Scribed by Prakash S. Nangia; Sidney W. Benson

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
590 KB
Volume
12
Category
Article
ISSN
0538-8066

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✦ Synopsis

Data on the liquid-phase oxidation of isobutane a t 50 and 100°C have been reexamined, using a modified mechanism to take into account the termination by isohutylperoxy radicals. Algebraic expressions are derived from steady-state methods. Using Arrhenius parameters fitted by transition-state A factors and activation energies derived from observed "best" rate constants, new sets of parameters are derived for the rate constants for propagation by t-BuOz

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