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Liquid Phase Oxidation of Alkenes with Nitrous Oxide to Carbonyl Compounds

✍ Scribed by E. V. Starokon; K. A. Dubkov; D. E. Babushkin; V. N. Parmon; G. I. Panov

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
128 KB
Volume
346
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

A variety of substrates including linear, cyclic, heterocyclic alkenes and their derivatives were tested in the liquid phase non‐catalytic oxidation with nitrous oxide (N~2~O). The structure and composition of the alkenes have a significant effect on the reaction selectivity. With many alkenes, N~2~O oxidation provides a selective way for the preparation of carbonyl compounds. The generation of carbene (or diazomethane) species is a remarkable feature of the oxidation of terminal alkenes.

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