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Liquid-phase oxidation of 1-isopropyl- and 1-ethyl-4-methoxybenzenes with oxygen to hydroperoxides

✍ Scribed by Jan Zawadiak; Zbigniew Stec; Bartłomiej Jakubowski; Beata Orlińska

Book ID
102443243
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
115 KB
Volume
35
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A study was carried out on the kinetics of free‐radical chain oxidation of 1‐isopropyl‐4‐methoxybenzene (1a) and 1‐ethyl‐4‐methoxybenzene (1b) with oxygen in the liquid phase to yield 1‐methyl‐1‐(4‐methoxyphenyl)ethyl hydroperoxide (2a) and 1‐(4‐methoxyphenyl)ethyl hydroperoxide (2b). The oxidizability of 1a and 1b was studied over the temperature range 50–100°C. Long‐term oxidations of 1a and 1b to the corresponding hydroperoxides were carried out and the properties and thermal stability of 2a were established. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 35: 89–94, 2003

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The liquid-phase oxidation of isomeric m
The liquid-phase oxidation of isomeric methoxy-(1-methylethyl)benzenes with oxygen to the hydroperoxides
✍ Jan Zawadiak; Bartłomiej Jakubowski; Zbigniew Stec 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 99 KB

## Abstract The kinetics of liquid‐phase oxidation of 1‐methoxy‐2‐(1‐methylethyl)benzene (**1a**), 1‐methoxy‐3‐(1‐methylethyl)benzene (**1b**), and 1‐methoxy‐4‐(1‐methylethyl)benzene (**1c**) with oxygen as oxidant to yield the corresponding 1‐methyl‐1‐(2‐methoxyphenyl)ethyl (**2a**), 1‐methyl‐1‐(3