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Liquid phase benzylation of benzene and toluene with benzyl alcohol over modified zeolites

✍ Scribed by N. Narender; K.V.V. Krishna Mohan; S.J. Kulkarni; I. Ajit Kumar Reddy


Book ID
119215533
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
206 KB
Volume
7
Category
Article
ISSN
1566-7367

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The catalytic activity of gel and macroreticular ion-exchange resins (Lewatit and Amberlyst-15) was evaluated for the reaction of benzene with benzyl alcohol and benzyl chloride at 80Β°C in the liquid phase. With benzyl chloride, the monobenzylation product, diphenylmethane, was obtained in low yield

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Various solid acids were investigated for the liquid-phase benzylation of aromatics to industrially important substituted diphenylmethanes. Large-pore zeolites, particularly H-beta (BEA), were active and regioselective for the parasubstituted product in the benzylation of arenes. With deactivated ar