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Liquid-phase autoxidation of organic compounds at elevated temperatures. 2. Kinetics and mechanisms of the formation of cleavage products in n-hexadecane autoxidation

โœ Scribed by Jensen, R. K.; Korcek, S.; Mahoney, L. R.; Zinbo, M.


Book ID
126177146
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
876 KB
Volume
103
Category
Article
ISSN
0002-7863

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Liquid-phase autoxidation of organic com
โœ R. K. Jensen; S. Korcek; M. Zinbo ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 434 KB

The absolute rate constants for the intermolecular hydrogen abstraction reactions of secondary hydrogens by secondary alkylperoxy radicals in hexadecane autoxidation, k 3 , have been determined in the temperature range of 120-190ยฐC using the stirred flow reactor technique. Absolute rate constants de