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Liquid Crystallinity of Unsymmetrical Ferrocene Derivatives (I) Synthesis of Unsymmetrically 1,1′-Disubstituted Ferrocene Derivatives and their Phase Transition Behavior

✍ Scribed by Hanasaki, Tomonori; Matsushita, Keishi; Watanabe, Tokiko; Enomoto, Satomi; Sato, Yuta

Book ID
126973176
Publisher
Taylor and Francis Group
Year
2000
Tongue
English
Weight
292 KB
Volume
351
Category
Article
ISSN
1058-725X

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Acylation of benzyl ferrocenecarboxylate 3 with benzoyl chloride affords the known ferrocene keto-acid 5 in one step and provides a convenient entry to a variety of unsymmetrical l,l'-substituted ferrocene derivatives. Similar acylation procedures have been employed to bridge two ferrocene units lea