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Liquid crystalline side chain-coil diblock copolymers by living free radical polymerization

✍ Scribed by Maria C. Bignozzi; Christopher K. Ober; Michele Laus


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
75 KB
Volume
20
Category
Article
ISSN
1022-1336

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✍ Wan, Xinhua; Tu, Yingfeng; Zhang, Dong; Zhou, Qifeng 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 97 KB 👁 1 views

The synthesis of rod±coil diblock copolymers with narrow polydispersity was achieved for the ®rst time by TEMPO-mediated `living' free radical polymerization of styrene and 2,5-bis[(4methoxyphenyl)oxycarbonyl]styrene. The block architecture of the two diblock copolymers thus prepared, MPCS-block-St