## Abstract **Summary:** New __p__‐xylylenebis‐(oxa‐thia‐propan) bridged metal‐free and metallophthalocyanine polymers were synthesized. The metal‐free phthalocyanine polymer (**3**) was prepared by the reaction of a tetranitrile monomer with 1,8‐diazabicyclo[5.4.0]undec‐7‐ene (DBU) in pentanol. Ni
Liquid crystalline oligomeric and polymeric phthalocyanines
✍ Scribed by Prof. Michael J. Cook
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 337 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0935-9648
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📜 SIMILAR VOLUMES
## Abstract Bridged polymeric phthalocyanines exist in different isomeric forms of varying symmetry. The number of isomers and the symmetry depends on the structure, i. e. the size and shape, of the polymeric phthalocyanine. Equations are derived for calculating the number of isomers for bridged po
A series of methyl-terminated oligooxyethylene ( CH ~3~( OCH ~2~ CH ~2~)~n~ O , n = 8.8)-substituted phthalocyanines with peripheral substitution at four β positions, at four α positions and at the eight α positions was synthesized and structurally characterized. These compounds are isotropic liquid
TEM images of polymers from 5 c obtained after 60 s irradiation at 65 8C in the liquid crystalline state (a) and at 100 8C in the isotropic state (b).