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Liquid ammonia solutions of [BF4]−, [ClO4]− and [PF6]− salts : a raman and nmr study

✍ Scribed by D.J. Gardiner; N. Daneshvar; B.P. Straughan

Publisher
Elsevier Science
Year
1981
Weight
214 KB
Volume
20
Category
Article
ISSN
0378-4487

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✦ Synopsis

Raman and proton nmr spectra of liquid NH 3 and liquid ND 3 solutions of tetrafluoroborate [BF4]-perchlorate [Cl04]-and [PFb]-salts have been studied.

Ammonia-cation interactions were found to be dominant and no evidence for anioncation or anion-solvent interactions was found, indicating a similarity of behaviour for these anions in both aqueous and ammonia solutions.

📜 SIMILAR VOLUMES

Syntheses, crystal structures and Raman
Syntheses, crystal structures and Raman spectra of Ba(BF4)(PF6), Ba(BF4)(AsF6) and Ba2(BF4)2(AsF6)(H3F4); the first examples of metal salts containing simultaneously tetrahedral BF4− and octahedral AF6− anions
✍ Matic Lozinšek; Tina Bunič; Evgeny Goreshnik; Anton Meden; Melita Tramšek; Gašpe 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 583 KB

In the system BaF 2 /BF 3 /PF 5 /anhydrous hydrogen fluoride (aHF) a compound Ba(BF 4 )(PF 6 ) was isolated and characterized by Raman spectroscopy and X-ray diffraction on the single crystal. Ba(BF 4 )(PF 6 ) crystallizes in a hexagonal P62m space group with a ¼ 10.2251(4) Å, c ¼ 6.1535(4) Å, V ¼ 5

ChemInform Abstract: Syntheses, Crystal
ChemInform Abstract: Syntheses, Crystal Structures and Raman Spectra of Ba(BF4)(PF6), Ba(BF4)(AsF6) and Ba2(BF4)2(AsF6) (H3F4). The First Examples of Metal Salts Containing Simultaneously Tetrahedral BF-4 and Octahedral AF-6 Anions.
✍ Matic Lozinsek; Tina Bunic; Evgeny Goreshnik; Anton Meden; Melita Tramsek; Gaspe 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

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