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Lipophilic disulfide prodrugs — syntheses and disulfide bond cleavage

✍ Scribed by Müller, Christa E.; Daniel, Peter T.; Holzschuh, Joachim; Roth, Hermann J.

Book ID
123189802
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
473 KB
Volume
57
Category
Article
ISSN
0378-5173

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## Abstract Reaction of the disulfide {HpicanS}~2~ (HpicanS is the carboxamide based on picolinate (pic) and __o__‐mercaptoaniline (anS); the {} brackets are used to denote disulfides) with [VOCl~2~(thf)~2~] leads to reductive scission of the disulfide bond and formation of the mixed‐valence (V^IV^