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Lipase-mediated acyl-exchange reactions with butteroil in anhydrous media

โœ Scribed by Jerome M. Elliott; Kirk L. Parkin

Book ID
112816160
Publisher
Springer-Verlag
Year
1991
Tongue
English
Weight
763 KB
Volume
68
Category
Article
ISSN
0003-021X

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Indium-mediated reaction of acyl cyanides 1 with prop-2-ynyl bromides 2 in aqueous media occurs regioselectively to afford either allenic 3 or propargylic ketones 4 depending on the g-substituent of the prop-2-ynyl bromide under the mild conditions.