𝔖 Bobbio Scriptorium
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Lipase-catalyzed synthesis of β-methylglucoside esters containing an α-hydroxy acid

✍ Scribed by Dae-Won Park; Ji-Seok Kim; Seungjoo-Haam; Hae-Sung Kim; Woo-Sik Kim


Book ID
110324051
Publisher
Springer Netherlands
Year
2001
Tongue
English
Weight
81 KB
Volume
23
Category
Article
ISSN
0141-5492

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Stereoselective synthesis of β-hydroxy-α
✍ Masahiro Hirama; Satoru Masamune 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 199 KB

Both threo-and erythro-8-hydroxy-u-methylcarboxylic acid thiol esters are stereoselectively synthesized through an aldol-type condensation of vinyloxyboranes derived formally from S-tertbutyl propanethioate. The basic carbon skeletons of many macrolide antibiotics are biosynthesized through a serie