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Lipase-Catalyzed Synthesis of Carboxylic Amides: Nitrogen Nucleophiles as Acyl Acceptor

✍ Scribed by Fred van Rantwijk; Michiel A. P. J. Hacking; Roger A. Sheldon

Book ID
106214868
Publisher
Springer Vienna
Year
2000
Tongue
English
Weight
272 KB
Volume
131
Category
Article
ISSN
0026-9247

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Lipase and esterase-catalyzed acylation
Lipase and esterase-catalyzed acylation of hetero-substituted nitrogen nucleophiles in water and organic solvents
✍ Michiel A. P. J. Hacking; HΓΌseyin Akkus; Fred van Rantwijk; Roger A. Sheldon πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 110 KB πŸ‘ 2 views

The lipase- and esterase-catalyzed acylations of hydroxylamine and hydrazine derivatives with octanoic acid and ethyl octanoate are described. The influence of solvent and nucleophile on the initial reaction rate was investigated for a number of free and immobilized enzymes. Initial rates were highe