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Lipase-Catalyzed Ring-Opening Polymerization of the O -Carboxylic Anhydride Derived from Lactic Acid

✍ Scribed by Bonduelle, Colin; Martin-Vaca, Blanca; Bourissou, Didier

Book ID
120817509
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
450 KB
Volume
10
Category
Article
ISSN
1525-7797

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Monomer versus Alcohol Activation in the 4-Dimethylaminopyridine-Catalyzed Ring-Opening Polymerization of Lactide and Lactic O-Carboxylic Anhydride
✍ Colin Bonduelle; Blanca Martín-Vaca; Fernando P. Cossío; Didier Bourissou 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 446 KB

## Abstract Model reactions for the 4‐dimethylaminopyridine (DMAP)‐catalyzed ring‐opening polymerization of lactide and the corresponding lactic __O__‐carboxylic anhydride (lacOCA) have been studied computationally at the B3LYP/6–31G(d) level of theory. The solvent effect of dichloromethane was tak