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Lipase-catalyzed ring-opening polymerization of 1,3-dioxan-2-one

โœ Scribed by Shiro Kobayashi; Hirofumi Kikuchi; Hiroshi Uyama

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
249 KB
Volume
18
Category
Article
ISSN
1022-1336

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โœฆ Synopsis

Abstract

Enzymatic ringโ€opening polymerization of a 6โ€membered cyclic carbonate, 1,3โ€dioxanโ€2โ€one, was investigated by using lipase as catalyst in bulk. Supported lipase derived from Candida antarctica catalyzed the polymerization to give the corresponding aliphatic polycarbonate. Unchanged monomer was recovered in the absence of the enzyme or using an inactivated enzyme, indicating that the present polymerization proceeds through enzymatic catalysis.

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