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Lipase-catalyzed regioselective acylation of diosgenyl saponins

✍ Scribed by Biao Yu; Guowen Xing; Yongzheng Hui; Xiuwen Han


Book ID
104231112
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
85 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


Diosgenyl saponins were regioselectively acylated by Novozyme 435 with vinyl esters as acylating agents in THF to afford the corresponding mono-or diacyl diosgenyl saponins.


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Lipase-catalyzed regioselective acylatio
✍ Manuel Ferrer; M. Angeles Cruces; Manuel BernabΓ©; Antonio Ballesteros; Francisco πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 105 KB πŸ‘ 2 views

The enzymatic synthesis of 6-O-lauroylsucrose and 6-O-palmitoylsucrose was performed by transesterification of sucrose with the corresponding vinyl esters in a medium constituted by two solvents. More specifically, the acylation was carried out in 2-methyl-2-butanol (tertamyl alcohol) containing a l