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Lipase-catalyzed asymmetric synthesis of oxathiazinanones through dynamic covalent kinetic resolution

✍ Scribed by Hu, Lei; Zhang, Yan; Ramström, Olof

Book ID
126792801
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
170 KB
Volume
12
Category
Article
ISSN
1477-0520

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The enzymatic dynamic kinetic resolution of N-acylhemiaminals by various lipases, namely, lipase PS, lipase AK and lipase QL, has been investigated. The acetylation of racemic N-acylhemiaminals with lipases exclusively produced the (R)-enantiomers in enantiomerically pure form and quantitative yield