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Linear viscoelastic behavior of the Hookean dumbbell with internal viscosity

โœ Scribed by Chi C. Hua; Jay D. Schieber; Charles W. Manke


Publisher
Springer-Verlag
Year
1996
Tongue
English
Weight
769 KB
Volume
35
Category
Article
ISSN
0035-4511

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โœฆ Synopsis


The linear viscoelastic modulus G(t) predicted by the analytical formulations of Schieber (1993), Wedgewood (1993), Dasbach et al. (1992), and Booij and van Wiechen (1970) for the free-draining Hookean dumbbell with internal viscosity (IV) are compared with exact analytical results and exact numerical results obtained from Brownian dynamics simulations. All of these analytical formulations employ the Booij and van Wiechen expression for the IV force, thereby eliminating errors associated with linearization of the "deformational" velocity, however the theories differ in the approximations employed to solve configuration moment equations. Comparison with the exact G(t) results provides a means of testing these approximations. The approximate theories all correctly predict the singular part of G(t) at t = 0, providing correct predictions of r/', however deviations from the exact G(t) are seen in all cases for t>0.


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