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Linear Trinuclear Mixed-Metal Co II −Gd III −Co II Single-Molecule Magnet: [L 2 Co 2 Gd][NO 3 ]·2CHCl 3 (LH 3 = (S)P[N(Me)NCH−C 6 H 3 -2-OH-3-OMe] 3 )

✍ Scribed by Chandrasekhar, Vadapalli; Pandian, Balasubramanian Murugesa; Azhakar, Ramachandran; Vittal, Jagadese J.; Clérac, Rodolphe

Book ID
121416078
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
156 KB
Volume
46
Category
Article
ISSN
0020-1669

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Two new octadecanuclear clusters [Cu 12 Ln 6 ( 3 -OH) 24 (C 5 H 5 NCH 2 CO 2 ) 12 (H 2 O) 18 ( 9 -NO 3 )] (PF 6 ) 10 (NO 3 ) 7 ' 12H 2 O [Ln III ‫؍‬ Sm III (1) or Gd III (2)] have been synthesized and characterized by X-ray di4raction. They are isomorphous and crystallize in the triclinic space grou