Linear solvation energy relationships. Part 1. Solvent polarity?polarizability effects on infrared spectra
β Scribed by Kamlet, Mortimer J.; Taft, Robert W.
- Book ID
- 111919476
- Publisher
- Royal Society of Chemistry
- Year
- 1979
- Tongue
- English
- Weight
- 679 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
The solv3rochromlccqu311ons dcscnbmg rbe cifects of solvent polar~ty/polwizab~hty (IT\*), solvenr hydrogen band donor acIdtry (a). and solbent hydrozcn bond xccptor bJsiaty (I?) have been determmed for scvcd Iluabundazole homologurs The s rosificlcnt ws iound to bc hnearly rclstcd to rhe Hammett o\*
## Abstract The solvatochromic comparison method is used to unravel solvent polarity and hydrogen bonding effects on a variety of NMR spectral shifts and coupling constants. Solvent effects are rationalized in terms of the solvatochromic parameters Ο\*, Ξ΄, Ξ± and Ξ². Properties analyzed include ^19^F