Linear polythioesters—XXIV. Products of interfacial polycondensation of bis(4-mercaptomethylphenyl)sulphone with some aliphatic and phthaloyl dichlorides
✍ Scribed by Wawrzyniec Podkościelny; Wiesław Rudź
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 305 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
New polythioesters were obtained by interracial polycondensation of bis(4-mercaptomethylphenyl) sulphone with some aliphatic and phthaloyl dichlorides. To determine optimal conditions for polycondensation, the polythioester from bis(4-mercaptomethylphenyl)sulphone and sebacoyl chloride was chosen as a model system. The structures of polythioesters were determined by elemental analysis, infrared spectra (i.r.) and X-ray analysis. Thermal properties were examined by thermogravimetric analysis. Some physicochemical, mechanical and electrical properties have been studied.
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New polythioesters by interfacial polycondensation of 4,6-di(mercaptomethyl)-1,2,3,-trimethylbenzene, 3,5-di(mercaptomethyl)-1,2,4,-trimethylbenzene and 2,4-di(mercaptomethy1)-1,3,5-trimethylbenzene with adipoyl and sebacoyl chlorides were obtained. Process of polycondensation was carried out under