Linear free energy relationships applied to the reactivity and the 13C NMR chemical shifts in 4-[[(substituted phenyl)imino]methyl]benzoic acids
✍ Scribed by Aleksandar D. Marinković; Bratislav Ž. Jovanović; Fathi H. Assaleh; Vlatka V. Vajs; Milan I. Juranić
- Book ID
- 113806011
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 359 KB
- Volume
- 1011
- Category
- Article
- ISSN
- 0022-2860
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Linear free energy relationships (LFER) were applied to the 1 H and 13 C NMR chemical shifts (d N , NZ 1 H and 13 C, respectively) in the unsaturated backbone of cross-conjugated trienes 3-methylene-2-substituted-1,4-pentadienes. The NMR data were correlated using five different LFER models, based o
## Abstract The reactivities of 2‐(4‐substituted phenyl)‐cyclohex‐1‐enecarboxylic acids, 2‐(4‐substituted phenyl)‐benzoic acids, and 2‐(4‐substituted phenyl)‐acrylic acids with diazodiphenylmethane in various solvents were investigated. To explain the kinetic results through solvent effects, the se