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Linear and angular annelation effects on the 13C NMR spectra of tricyclic aromatic ketones. 1—annelated indanones

✍ Scribed by G. W. Buchanan; M. E. Isabelle; R. H. Wightman

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
317 KB
Volume
16
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon‐13 NMR chemical shifts are reported for nine tricyclic aromatic ketones formally derived from indanone. The influences of remote ring size, as well as linear, angular exo and angular endo ketone orientation are examined. Results are compared with available ^1^H NMR data. For indanone itself, based on selective ^1^H decoupling experiments, a recently reported CIDNP derived ^13^C signal assignment is shown to be in error.

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