Line shapes and photon echoes within a generalized Kubo model

✍ Scribed by J.R Schmidt; N Sundlass; J.L Skinner

• Publisher: Elsevier Science
• Year: 2003
• Tongue: English
• Weight: 296 KB
• Volume: 378
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/s0009-2614(03)01317-4

✦ Synopsis

Kubo introduced a stochastic model of frequency fluctuations that naturally leads to an understanding of homogeneous and inhomogeneous broadening in condensed phase spectroscopy. In this Letter we discuss a generalized Kubo model that has two different timescales. The model is relevant for a variety of different physical situations, and in certain limits describes combined homogeneous and inhomogeneous broadening. We explore the limits of applicability of this homogeneous/inhomogeneous phenomenology for both the line shape and the integrated two-pulse photon echo intensity. Our results have implications for non-linear ultrafast liquid-state spectroscopy.