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Limitations in the Use of Surface Tension and the Gibbs Equation To Determine Surface Excesses of Cationic Surfactants

✍ Scribed by Li, Pei Xun; Thomas, Robert K.; Penfold, Jeffrey


Book ID
126223308
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
903 KB
Volume
30
Category
Article
ISSN
0743-7463

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Molecular simulation of the surface tens
✍ Divesh Bhatt; Raymen Chee; John Newman; C.J. Radke πŸ“‚ Article πŸ“… 2004 πŸ› Elsevier Science 🌐 English βš– 101 KB

We present molecular dynamics simulations of the surface tension of aqueous NaCl and NaBr electrolyte solutions as a function of concentration at 300 K. With explicit water and Lennard-JonesyCoulomb ions of fixed charge, we find a positive Gibbs adsorption of both salts at higher concentrations of s