The origin of the lignin-carbohydrate bonding in a ljgnin-carbohydrate complex isolated by a modified Bj6rkman procedure is discussed. The results obtained from sugar analysis, methylation analysis, deuterium labelling of reducing end groups and gel permeation chromatography are used to evaluate dif
Lignin-carbohydrate bonds in a residual soda spruce pulp lignin
✍ Scribed by B. Košíková; A. Ebringerová
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 289 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0043-7719
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✦ Synopsis
The behaviour of lignin-polysaccharide complex of spruce wood in soda pulping was studied by the characterization of lignin-saccharide fractions isolated from a series of soda pulps. The dioxane pulp lignins contain 8-14% of carbohydrates in which glucose was the predominant component. Its content increased with increasing degree of delignification indicating the formation of secondary lignin-carbohydrate linkage. Both glycosidic and ether type of bond between residual lignin and cellulose in pulp was proved by methylation analysis of the pulp dioxane lignin.
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A lignin-carbohydrate material from black spruce (Picea mariana) was treated with a hemicellulase mixture. The carbohydrates in the remaining material were studied by the following methods, a) Treatment with 0.1 M NaOH in the presence of sodium borohydride followed by selective hydrolysis of the fur