## Abstract The rms radii of gyration γ__S__^2^γ^1/2^ and second virial coefficients Ξ~2~ of five monodisperse polystyrenes (__M__ Γ 10^β5^ = 1.6, 2.8, 4.2, 6.6) were measured in isorefractive tolueneβpoly(methyl methacrylate) (MΜ~v~ = 4.0 Γ 10^4^, 1.6 Γ 10^5^, and 6.3 Γ 10^5^) βsolvents.β For a gi
β¦ LIBER β¦
Light scattering studies on unfractionated poly(n-docosyl methacrylate)
β Scribed by Levi, D. W. ;Valles, R. J. ;Schramm, E. C.
- Book ID
- 104532050
- Publisher
- John Wiley and Sons
- Year
- 1962
- Weight
- 329 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3832
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
Poly(nβdocosyl methacrylate) was prepared by emulsion polymerization. Since the weightβaverage molecular weight of the unfractionated material appeared to be unusually large, light scattering measurements were made in three solvents and at several temperatures. No evidence of association in solution was found. Values of average molecular weight, dimensions, and second virial coefficients are reported.
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