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Light scattering characterisation of polymers II. Analyses of high molecular weight polystyrene

✍ Scribed by Suzuki, Hidematsu


Publisher
Wiley (John Wiley & Sons)
Year
1979
Tongue
English
Weight
648 KB
Volume
11
Category
Article
ISSN
0007-1641

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✦ Synopsis


Abstract

For light scattering analysis of an extremely high molecular weight polymer with large size in solution, use of mixtures of a given polymer with its low molecular weight homologue is described to have great advantages. With such bimodal mixtures as test samples, one can alter the unknown form of the angular variations of scattered lights to a form to be expected and widen the range of the linearity with sin^2^ (ΓΈ/2), where ΓΈ is the scattering angle. According to the considerations, a sample of linear polystyrene was successfully analysed on a commercial apparatus, Fica 50 to have the weight‐average molecular weight of 27 million.


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