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Ligand-to-Ligand Charge Transfer in (2,2′-Biquinoline)bis(cyclopentadienyl)zirconium(IV) – Absorption and Emission in the Visible Range

✍ Scribed by Horst Kunkely; Arnd Vogler


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
83 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis


The lowest energy electronic transition of [(cyclopenta-the Cp -Ǟ biq ligand-to-ligand charge-transfer-type. dienyl) 2 Zr IV (2,2Ј-biquinoline)] 2+ , which appears in absorption at λ max = 360 nm and in emission at λ max = 518 nm, is of