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Ligand substitution in the mixed-metal cluster PhCCo2Ni(CO)6Cp by 2,3-bis(diphenylphosphino)maleic anhydride (bma): An intimate picture involving the stepwise conversion of the trinuclear cluster PhCCo2Ni(CO)4(η2-bma)Cp to the mononuclear compound CpNi[PPh2CPhCC(PPh2)C(O)OC(O)]

✍ Scribed by Simon G. Bott; Kaiyuan Yang; Michael G. Richmond

Book ID
108188014
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
434 KB
Volume
690
Category
Article
ISSN
0022-328X

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📜 SIMILAR VOLUMES

Phosphine Ligand Attack at Both the Meth
Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in HCCo 2 NiCp(CO) 6 by 2,3-Bis(diphenylphosphino)maleic Anhydride (bma): P−C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co 2 NiCp(CO) 4 (μ-CO)[μ 2 ,η 2 ,η 1 -C(H)PPh 2 CC(PPh 2 )C(O)OC(O)] and Co 2 NiCp(CO) 4 [μ 2 ,η 2 ,σ-C(H)PPh 2 CCC(O)OC(O)](μ 2 -PPh 2 )
✍ Bott, Simon G.; Yang, Kaiyuan; Talafuse, Kathleen A.; Richmond, Michael G. 📂 Article 📅 2003 🏛 American Chemical Society 🌐 English ⚖ 148 KB