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Ligand Structural Effects on Cu 2 S 2 Bonding and Reactivity in Side-On Disulfido-Bridged Dicopper Complexes

✍ Scribed by Brown, Eric C.; Bar-Nahum, Itsik; York, John T.; Aboelella, Nermeen W.; Tolman, William B.


Book ID
127091681
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
330 KB
Volume
46
Category
Article
ISSN
0020-1669

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## Abstract Reaction of copper(I) bromide with benz‐1,3‐imidazole‐2‐thione (bzimtH~2~) in the presence of one equivalent of triphenylphosphane (PPh~3~), tri‐__meta__‐tolylphosphane (tmtp) or tri‐__para__‐tolylphosphane (tptp) in acetonitrile/methanol solvent afforded dinuclear complexes formulated