Diene ligands /
Ligand redistribution reactions of some organometallic rhodium and iridium complexes
β Scribed by Peter J. Stang; Yo-Hsin Huang
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 457 KB
- Volume
- 435
- Category
- Article
- ISSN
- 0022-328X
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π SIMILAR VOLUMES
Fast atom bombardment (FAB) mass spectrometry has been used to examine a series of rhodium, iridium and platinum orgmometaUic complexes, in wbich a cumdene ligand is attached to the metal in either uor bonding fashion. The most intense ion formed in the rhodium and platinum series is the metal-bis(t
Some new Rh(1) and Ir(1) complexes of the types [(COD)M(LL)]ClO, and [(COD)MCI], [COD = cyclooctadiene; M = Rh, Ir; LL = 1,l'-bis(dipheny1phosphino)ferrocene (DPPF), 1 -diphenylphosphino-2-(N,N-dimethylamino)methylferrocene (FcNP), 1,6-diferrocenyl-2,5diazahexane (FcNN)] were prepared, and their cat