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Ligand Oxidations in High-Spin Nickel Thiolate Complexes and Zinc Analogues

✍ Scribed by Chohan, Balwant S.; Shoner, Steven C.; Kovacs, Julie A.; Maroney, Michael J.

Book ID
125968941
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
182 KB
Volume
43
Category
Article
ISSN
0020-1669

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## Abstract The reactivity of the two nickel complexes [Ni(xbsms)] and [Ni(bsms)~2~] [H~2~xbsms = Ξ±,α′‐bis(4‐mercapto‐3,3‐dimethyl‐2‐thiabutyl)‐__o__‐xylene; Hbsms = 4‐mercapto‐3,3‐dimethyl‐1‐phenyl‐2‐thiabutane] towards copper iodide and zinc bromide has been investigated. The reactions yield nove

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The oxidative dehydrogenation of coordinated amine ligands in a variety of nickel and iron complexes' and several ruthenium complexes 2 has been reported,and electrochemical oxidative dehydrogenation of a copper complex has also been suggested3. In addition, nickel-coordinated B-amino ketimine