Ligand Functionalization, Reactivity, and Transformation at the Selenide Centers of [Pt 2 (μ-Se) 2 (PPh 3 ) 4 ] with Organic Halides
✍ Scribed by Yeo, Jeremy S. L.; Vittal, Jagadese J.; Henderson, William; Hor, T. S. Andy
- Book ID
- 126236267
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 110 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0276-7333
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📜 SIMILAR VOLUMES
Activity of [Pt 2 (-S) 2 (PPh 3 ) 4 ] (1) towards 1,4-dichlorobutane, 1,2-dichloroethane, ␣-␣ -dichloro-o-xylene and ␣-␣dichloro-m-xylene and the catalytic role of 1 in the syntheses of organosulfur materials was studied by in situ electrospray mass spectroscopy (ESMS). An intermediate, [Pt 2 (-SC 2
which are the first mononuclear thio-and selenocarbonyl complexa of platinum(0). The most common method of generating a CS or CSe ligand in the coordination sphere of a transition metal, namely the abstraction of a sulfur or selenium atom from coordinated CS2 or CSe2 by ph~sphanes~,~', has failed t