Ligand exchange reactions of N-donor ligands in cyclopalladated complexes
✍ Scribed by R.Ma. Ceder; M. Gómez; J. Sales
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 470 KB
- Volume
- 361
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
It is possible to study the very rapid exchange rates between molecules or ions, L, coordinated to paramagnetic ions and the jiee molecules or ions, L\*, in the body of the solution by measuring the line width of the N M R signal of L\*.
## Abstract A number of cobalt(II) chloride complexes of pyridine/amine N~3~ and N~4~ donors have been prepared and structurally characterised. Even though they are paramagnetic, assignment of the ^1^H NMR signals was possible in several cases. With the exception of tpa, which formed a cationic mon
Thermodynamic data on complex formation between nitrogen donor ligands (amines, pyridines) and group 11 monovalent ions in water and non-aqueous media are reviewed here. Particular emphasis is paid to Ag(I) complex formation in water and dimethylsulfoxide (DMSO), due to the amount and quality of dat