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Ligand Effects on the Reactivity of CuIL Complexes Towards Cl3CCO2−

✍ Scribed by Nadav Navon; Ariela Burg; Haim Cohen; Rudi van Eldik; Dan Meyerstein

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
321 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✍ Sonja Pavlik; Michael Puchberger; Kurt Mereiter; Karl Kirchner 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB

## Abstract The air‐sensitive DMF‐containing intermediate [RuTp(PR~3~)(Cl)(DMF)] is formed by refluxing a DMF solution of [RuTp(COD)Cl] (1) in the presence of at least 1 equiv. of PR~3~ (PR~3~ = PPh~3~, PPh~2~__i__Pr, P__i__Pr~3~, and PCy~3~). On exposure to air in the presence of CCl~4~, this comp