Ligand effects in palladium-catalyzed Suzuki and Heck coupling reactions
✍ Scribed by M. Emre Hanhan
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 269 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.1389
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## Abstract A novel route to prepare polyaniline (PANI)‐supported Pd(0) nanoparticles by a one‐pot chemical route is presented. Nanosized Pd(0) particles were first prepared by reduction of Pd(OAc)~2~ using __t__‐BuONa activated sodium hydride in refluxing THF. A ligand exchange with aniline on __t
## Abstract A novel __C__~2~ symmetrical and sterically bulky thiourea ligand **1** has been successfully applied to Heck, Suzuki and Suzuki‐type carbonylative coupling reactions under aerobic conditions. Since the metal‐sulfur bond in the thiourea complexes is stronger than the metal‐phosphorus bo