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Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

✍ Scribed by Weiming Yuan; Shengming Ma

Book ID
111992652
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
348 KB
Volume
354
Category
Article
ISSN
1615-4150

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Addition of bis(pinacolato)diboroon [(Me,C,O,)B-B(O,C#e,)] to various allenes was carried out in excellent yields in the presence of Pt(PPh,), at 80 T or Pt(dba)J(c-Hex)g at 50 "c. The addition to internal double bond was predominant for monosubstituted allenes, whereas the terminal diboration produ

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