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Ligand control of the photostereochemistry of rhodium(III) tetraammine complexes, Rh(NH3)4XYn+. Cis to trans and trans to cis photoisomerization and photostationary states

✍ Scribed by Skibsted, L. H.; Ford, Peter C.

Book ID: 126975228
Publisher: American Chemical Society
Year: 1980
Tongue: English
Weight: 941 KB
Volume: 19
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic50209a002

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## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures