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Ligand chirality effect on the structure and its spectroscopic consequences in [Ln2(Ala)4(H2O)8] (C104)6 crystals

✍ Scribed by T. Glowiak; J. Legendziewicz; E. Huskowska; P. Gawryszewska


Book ID
103654171
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
752 KB
Volume
15
Category
Article
ISSN
0277-5387

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip