Ligand binding to the active site Fe(II) of gentisate 1,2-dioxygenase
✍ Scribed by M.R. Harpel; J.D. Lipscomb
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 81 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0162-0134
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## Abstract Modulation of the Fe redox levels within the diiron dithiolato carbonyls with the coordination of a redox‐active phosphane is reported. Treatment of [Fe~2~{μ‐S(CH~2~)~2~NR(CH~2~)~2~S}(CO)~6~]~2~ and [Fe~2~(μ‐pdt)(CO)~6~] with mppf affords the phosphane substituted species, [Fe~2~{μ‐S(CH
## Abstract Six‐membered heterocycles, 1,4‐dithiane and 1,4‐thioxane, were treated with [Fe~2~(CO)~6~(μ‐pdt)] (pdt = propanedithiolate) in order to synthesise [2Fe3S] complexes with well positioned heteroatoms as potential base. Monosubstituted compounds of general formula [Fe~2~(CO)~5~L(μ‐pdt)] (L