Ligand and loop variations at type 1 copper sites: influence on structure and reactivity
✍ Scribed by Dennison, Christopher
- Book ID
- 120597862
- Publisher
- Royal Society of Chemistry
- Year
- 2005
- Tongue
- English
- Weight
- 306 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1477-9226
- DOI
- 10.1039/B507440C
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## Abstract Copper coordination complexes of the neutral tetradentate nitrogen‐containing ligands tris(3,5‐dimethylpyrazol‐1‐ylmethyl)amine (L0N4) and tris(3,5‐diisopropylpyrazol‐1‐ylmethyl)amine (L1N4), namely the copper(II) chlorido complexes [Cu^II^(L0N4)Cl~2~] (1) and [Cu^II^(L1N4)Cl~2~] (2), t
## Abstract The ligand α,α′‐bis{bis[1‐(1′‐methyl‐2′‐benzimidazolyl)methyl]amino}‐__m__‐xylene (L‐55) forms the complexes [Cu^I^~2~(L‐55)(MeCN)~2~](PF~6~)~2~ (1) and [Cu^II^~2~(L‐55)(OMe)~2~][ClO~4~]~2~ (2), in which an extremely weak axial amine interaction is imposed by the small five‐membered ben