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Ligand-aided photoreduction of iron-porphyrin complexes probed by resonance Raman spectroscopy

โœ Scribed by Ozaki, Y.; Iriyama, K.; Ogoshi, H.; Kitagawa, Teizo


Book ID
118270935
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
486 KB
Volume
109
Category
Article
ISSN
0002-7863

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Alcohol-catalyzed photoreduction of iron
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Photoreduction of Fe"'(OEP) (2-MeIm) (OEP is octaethylporphyrin; Z-MeIm is 2-methylimidazole) was found to be catalyzed by a trace amount of MeOH present m CH& as a stabilizer. The absence of either 2-Melm or MeOH in the CH&l, solution of Fe'n(OEP)X (X is Cl-, Br-or I-) leads to no photoreduction. T