Lifetime measurements of individual rotational levels in excited states of hafnium oxide and hafnium sulfide have been performed using population probing by resonant two-photon ionization in a molecular beam. For the b 3 1 state of HfO rotational levels in the vibrational level v = 0 were found to h
Lifetime Measurements of theC3Δ State of TiS and theE3Π State of TiO
✍ Scribed by C. Lundevall
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 138 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
✦ Synopsis
Lifetime measurements of the C 3 ⌬ electronic state of the titanium sulfide molecule and of the E 3 ⌸ electronic state of the titanium oxide molecule have been performed using population probing with resonant two-photon ionization in a molecular beam. The lifetimes for the TiS C 3 ⌬ 1 state were found to be 243 Ϯ 7 ns, 278 Ϯ 9 ns, and 286 Ϯ 15 ns for the v ϭ 0, v ϭ 1, and v ϭ 2 levels, respectively. The lifetime for the TiO E 3 ⌸ 0 state was found to be 4.9 Ϯ 0.2 s for the v ϭ 0 level.
📜 SIMILAR VOLUMES
Laser excitation spectra of TiO have been recorded in the 30 500-34 500 cm 01 energy region using the technique of optical-optical double resonance. Twenty 3 F and 24 3 P excited vibrational levels have been observed in experiments that use the A 3 F and B 3 P electronic states as intermediates. The
Explicitly correlated wavefunctions are used to compute adiabatic potential energy curves and electronic dipole transition moments for a number of triplet Sigma and Pi states of the hydrogen molecule in a wide range of internuclear distances. The potential energy curves are more accurate and complet